What is Grey Iron – Grey Cast Iron Composition, Properties, Grades, Uses, Grey vs Ductile Iron

2025.1.10

Grey cast iron is one of the most used materials for casting and machining. The versatility of gray cast iron makes it suitable for a wide range of uses in various industries! Why is it so good? Let’s take a detailed understanding of grey iron by breaking down its chemical composition (microstructure), physical & mechanical properties, characteristics, application, casting process, and the differences between grey iron and ductile iron!

What is Grey Iron?

Grey iron is a type of cast iron, so also known as Grey Cast Iron that contains flake-like graphite, and its name varies depending on the base structure. The name “gray” comes from the fact that the fracture surface is gray, or mouse-colored. Cast iron is an iron-carbon alloy with a high carbon content, and by definition contains 2.06 to 6.67% carbon. Gray cast iron is a material classified as ordinary cast iron among cast iron products.

Grey cast iron is abbreviated as FC, which is the abbreviation of iron (Fe) and casting, and a three-digit number indicating the tensile strength is written after FC. For example, FC150 means that the tensile strength of this gray cast iron is at least 150. It is called “flake graphite cast iron” because the graphite resembles a collection of petals. When gray cast iron and white cast iron are mixed and the fracture surface appears as black and white spots, it is sometimes called “mottled cast iron.

Grey Cast Iron Composition (Microstructure)

The main components of gray cast iron are iron (Fe) and carbon (C), but it also contains silicon (Si), manganese (Mn), phosphorus (P), and sulfur (S). Below is main chermical compostion:

Grey Cast Iron Properties

As the carbon content increases, the hardness also increases; thus, the properties change depending on which components are more prevalent. The basic properties of gray cast iron are as follows:

Grey Iron Mechanical Properties:

Grey Iron Physical Properties:

Grey Cast Iron Processing Methods

Gray cast iron is a material that is widely used as a machine part and structural material because of its excellent workability. We process it in various ways even for the production of test pieces, which is often requested at Disecasting-Mould.Com.

Here, we will explain the characteristics of casting, milling, lathe machining, polishing, and electric discharge machining, which are the typical methods used for cutting and processing test pieces of gray cast iron.

We can process grey cast iron using some of its processing machines (cutting machines, general-purpose machines, machining centers, NC lathes, surface grinders, and electric discharge machines) according to the request. Regarding the production of parts and jigs, consultation is required depending on the size and quantity.

Grey Iron Casting Process

Although grey iron has good mechanical properties and can be used in a variety of processing methods, its most commonly used processing method is casting. Its casting process mainly includes mold making, raw material preparation, smelting, pouring, cooling, demoulding, cleaning and heat treatment:

  1. First of all, mold making is the first step in the casting process, and its main purpose is to ensure the accuracy and surface quality of gray cast iron castings. The mold is usually made of materials such as gypsum, sand, graphite, etc., depending on the shape and size of the casting.
  2. Secondly, raw material preparation refers to the mixing of molten iron, pig iron, scrap steel and other additives in a certain proportion to make the raw materials of gray cast iron. This process is very important and determines the chemical composition and mechanical properties of the final casting.
  3. Then, smelting is the process of melting the raw materials at high temperature, usually in an electric arc furnace or furnace. During smelting, the temperature and melting time should be controlled to fully melt the raw materials and ensure the quality of the casting.
  4. Next, pouring is the process of pouring molten iron into the mold. During this process, care should be taken to avoid the generation of bubbles and inclusions to ensure the compactness and surface quality of the casting.
  5. Then, cooling and demolding are indispensable links in the casting process. A series of physical and chemical changes will occur in the casting during the cooling process, so the cooling rate should be controlled to avoid cracks and defects. When demolding, care should be taken to avoid damage to the surface of the casting.
  6. Finally, cleaning and heat treatment are the last two links in the casting process. Cleaning is to remove the oxide scale and residue on the surface of the casting to facilitate heat treatment. Heat treatment is the process of heating, heat preservation and cooling the gray cast iron casting to improve the mechanical properties and wear resistance of the casting.

Grey Cast Iron Applications

Grey cast iron has low friction due to the flake graphite acting as a lubricant, giving it excellent wear resistance. This makes it suitable for parts that experience significant wear, such as machine components and tools. Additionally, the flake graphite facilitates the escape of cutting tool edges and easily breaks up chips, making it a good material for machining. Compared to steel, it is easier to machine, allowing for the production of complex-shaped components.

However, some machining contractors may refuse to process grey cast iron. This is because the graphite contained in it can accumulate inside machine tools, adversely affecting their operation and machining accuracy. It is advisable to confirm in advance whether they can handle your request.

Given its excellent wear resistance and machinability, gray cast iron is used in the following applications:

Grey Cast Iron Grades & Types

Grey cast iron grades are typically classified based on their mechanical properties and the strength of the iron. Here’s a detailed look at the grades and types of grey cast iron worldwide:

Certainly! Adding the China National Standards (GB) for grey cast iron to the table will provide a more comprehensive overview, especially for users dealing with international specifications. Here’s the updated table including the GB grades:

StandardGradeMinimum Tensile StrengthApplication Examples
ASTM A48
Defines unalloyed grey cast iron grades based on minimum tensile strength for general applications in the U.S.
Class 2020 ksiGear boxes, engine blocks, machine bases
Class 2525 ksiCounter weights, pump housings
Class 3030 ksiValve bodies, pistons, bearing caps
Class 3535 ksiHigh-strength applications, heavy-duty gears
EN 1561
European standard specifying properties of unalloyed grey cast iron, focusing on hardness and wear resistance.
EN-GJL-150150 MPaGeneral engineering, housing frames
EN-GJL-200200 MPaEngine blocks, manifolds
EN-GJL-250250 MPaHeavy-duty gears, flywheels
EN-GJL-300300 MPaPress frames, stressed engine parts
EN-GJL-350350 MPaHighly stressed components in machinery
ISO 185
International standard that categorizes grey cast iron based on tensile strength for global applications.
ISO 185/150150 MPaFrames, housings, medium-strength applications
ISO 185/200200 MPaConstruction equipment, road machinery
ISO 185/250250 MPaIndustrial machines, high-strength parts
ISO 185/300300 MPaStressed parts in machinery and engines
JIS G5501
Japanese standard for grey cast iron, defining grades similar to ASTM and ISO for use primarily in Asia.
FC150150 MPaPipes, machine parts, general castings
FC200200 MPaMotor blocks, pumps, general machinery
FC250250 MPaHeavy-duty gears, machine tool parts
FC300300 MPaHeavy machinery, press frames
FC350350 MPaHighly stressed components, heavy-load gears
SAE J431
Specifies grey cast iron grades used in the automotive industry, particularly for components like brake drums and engine blocks.
G180018 ksiSuitable for products requiring low strength
G250025 ksiBrake drums, rotors, other automotive parts
G300030 ksiAutomotive engine blocks, cylinder heads
G350035 ksiHigher strength automotive components
G400040 ksiApplications requiring higher wear resistance
GB/T 9439
Chinese standard for grey cast iron, setting technical requirements for castings in engineering and automotive industries in China.
HT150150 MPaGeneral engineering, light castings
HT200200 MPaMachine bases, frames, boxes, heavier castings
HT250250 MPaGears, cylinder blocks, heavy-duty machinery
HT300300 MPaHeavy machinery, rollers, press frames
HT350350 MPaHeavy-duty gears, high-stress components

Grey Iron vs Ductile Iron: What are the Differences?

Alongside with Grey Iron, Ductile Iron is another most commonly used casting materials. Though they share some basic characteristics as they both belong to the iron casting family, their properties and applications differ significantly due to their distinct microstructures.

First of all, let take a overview of the table comparing the properties of gray cast iron and ductile cast iron:

PropertyGrey IronDuctile Iron
Graphite ShapeFlakySpherical
Tensile StrengthLowHigh
Compressive StrengthHighHigh
DuctilityLowHigh
Wear ResistanceHighVery High
MachinabilityVery HighHigh
Vibration DampingVery HighHigh
CostLowModerately High
Main UsesEngine blocks, manhole covers, cutting toolsWater pipes, vehicle parts, frying pans, railway wheels
This table only provides an overview, but it is important to consider specific properties and requirements when choosing materials.

Differences Between Grey Iron and Ductile Iron

Let’s explain the differences between them in more detail to help you figure out which one is better:

Graphite Shape

Grey Iron: Contains graphite in flake form. This flake-like structure contributes to the grey color seen on the fracture surfaces, hence the name “grey iron.”

Ductile Iron: Contains graphite in spherical form. The spherical shapes of graphite within the metal provide enhanced ductility and toughness, which improves the overall strength and impact resistance of the iron.

Mechanical Properties

Tensile Strength:

Grey Iron: Lower tensile strength due to the stress concentration effects of the flake graphite.

Ductile Iron: Higher tensile strength and better elongation properties, making it more suitable for dynamic and high-stress applications.

Compression Strength:

Both grey and ductile iron have high compression strength, but ductile iron’s additional ductility makes it more versatile under load.

Ductility

Grey Iron: Generally, has lower ductility compared to ductile iron, making it more brittle and susceptible to cracking under shock or impact.

Ductile Iron: Exhibits higher ductility, which allows it to withstand greater deformation before failing, making it ideal for applications requiring a higher resistance to impact.

Wear Resistance

Grey Iron: Offers good wear resistance, which makes it suitable for applications like engine blocks and machinery where durability is important.

Ductile Iron: Exhibits even higher wear resistance due to its tough structure, suitable for heavily stressed components like automotive drivetrain parts.

Machinability

Grey Iron: Excellent machinability due to the presence of graphite flakes which act as a lubricant during the cutting process.

Ductile Iron: Also machinable, but to a slightly lesser extent compared to grey iron due to its tougher nature.

Vibration Dampening

Grey Iron: Superior vibration dampening capabilities due to the graphite flake structure, making it a preferred material for bases of heavy machinery and engine blocks.

Ductile Iron: Also good at dampening vibrations but slightly less effective compared to grey iron.

Cost

Grey Iron: Typically less expensive to produce than ductile iron, mainly due to simpler processing requirements.

Ductile Iron: Generally costs more due to additional processing to achieve the spherical graphite shapes, but the cost is offset by the material’s superior properties.

Common Applications

Grey Iron: Widely used in applications such as engine blocks, manhole covers, and machinery bases where strength is required but where the material will not be subjected to bending or torsional stresses.

Ductile Iron: Used in applications that require additional toughness and strength, such as water pipes, automotive components, and gears.